The surface depletion layer controls the density and mobility of Selleckchem Seliciclib electrons in the ZnO nanorods. When the ZnO nanorods are exposed to hydrogen, the adsorbed oxygen releases the previously trapped electrons back to the conduction band. The depletion width decreases as a result of the decrease in surface oxygen. This results in an increase in electron concentration of ZnO nanorods and a decrease in height of the barrier

potential at the grain-grain contacts. Thus, the impedance of the ZnO nanorods decreases as the hydrogen concentration increases. Thus, it could be concluded that the hydrogen concentration significantly affects the grain boundary resistance which facilitates its detection. Table 1 Modeled RC parameters for Pd-sensitized ZnO nanorods under different H 2 concentrations at room temperature H2 (ppm) R gb (Ω) C PE (nF) p value 0 22,938 RG-7388 in vitro 4.99 0.89 40 11,950 3.53 0.9 100 9,950 3.5 0.9 200 6,550 2.938 0.91 300 4,780 2.88 0.91 360 3,765 2.83 0.91 However, the variation in the capacitance MK5108 mw values was not significant. This reflected that the hydrogen gas mainly affects the surface charge region of the grain boundaries of Pd-sensitized ZnO nanorods. The peak frequencies related to the relaxation frequencies of the impedance were also estimated by

plotting the −Z′′ versus the logarithmic frequency curve (Figure 7). It was observed that the imaginary part of impedance decreased as the gas concentration increased [2]. The decrement in the impedance imaginary part was related to the carrier concentrations. As the hydrogen concentration increases, the barrier height decreases causing more carriers to flow. This results in a decrease in impedance. It was also observed that the peak frequency shifted toward higher frequencies with increasing Endonuclease hydrogen concentration. The shifting of the peak towards high frequencies is related to an ease in the flow of charge carriers to the AC electric field [35]. The broadening of peak

with an increase in hydrogen concentration was due to the different distribution of relaxation time [33, 36]. The relaxation process may be due to the presence of electrons and/or immobile species [33]. Figure 7 Imaginary parts of impedance for Pd-sensitized ZnO nanorods under different H 2 concentrations at room temperature. The sensitivity of the fabricated ZnO nanorod sensor was evaluated as a function of frequency and hydrogen concentration using the equation given below: (4) where Z a represents the impedance of air and Z g represents the real part of impedance under hydrogen flow. Figure 8 displayed the effect of frequency at different parts per million (ppm) values of hydrogen on Pd-sensitized ZnO nanorods at room temperature. The sensitivity of our device at room temperature was better than the reported literature values at 400°C [2]. The noticeable change in the sensitivity was observed in the frequency range of 1 Hz to 100 kHz.